Article
Understanding the mechanism of short-range electron transfer using an immobilized cupredoxin.
Journal of the American Chemical Society - 25 Jul 2012
Monari Stefano, Battistuzzi Gianantonio, Bortolotti Carlo A, Yanagisawa Sachiko, Sato Katsuko, Li Chan, Salard Isabelle, Kostrz Dorota, Borsari Marco, Ranieri Antonio, Dennison Christopher, Sola Marco
Abstract excerpt
The hydrophobic patch of azurin (AZ) from Pseudomonas aeruginosa is an important recognition surface for electron transfer (ET) reactions. The influence of changing the size of this region, by mutating the C-terminal copper-binding loop, on the ET reactivity of AZ adsorbed on gold electrodes modified with alkanethiol self-assembled monolayers (SAMs) has been studied. The distance-dependence of ET kinetics...
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