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Article

Rationally tuning the reduction potential of a single cupredoxin beyond the natural range.

Nature - 5 Nov 2009

Marshall Nicholas M, Garner Dewain K, Wilson Tiffany D, Gao Yi-Gui, Robinson Howard, Nilges Mark J, Lu Yi

Abstract excerpt

Redox processes are at the heart of numerous functions in chemistry and biology, from long-range electron transfer in photosynthesis and respiration to catalysis in industrial and fuel cell research. These functions are accomplished in nature by only a limited number of redox-active agents. A long-standing issue in these fields is how redox potentials are fine-tuned over a broad range with little change to the...

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Identifiers

PMID: 19890331
DOI: 10.1038/nature08551
PMCID: PMC4149807

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