Article
Disentangling electron tunneling and protein dynamics of cytochrome c through a rationally designed surface mutation.
The journal of physical chemistry. B - 23 May 2013
Alvarez-Paggi Damián, Meister Wiebke, Kuhlmann Uwe, Weidinger Inez, Tenger Katalin, Zimányi László, Rákhely Gábor, Hildebrandt Peter, Murgida Daniel H
Abstract excerpt
Nonexponential distance dependence of the apparent electron-transfer (ET) rate has been reported for a variety of redox proteins immobilized on biocompatible electrodes, thus posing a physicochemical challenge of possible physiological relevance. We have recently proposed that this behavior may arise not only from the structural and dynamical complexity of the redox proteins but also from their interplay with...
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