Article
Gated electron transfer of cytochrome c6 at biomimetic interfaces: a time-resolved SERR study.
Physical chemistry chemical physics : PCCP - 14 Sept 2009
Kranich Anja, Naumann Hendrik, Molina-Heredia Fernando P, Moore H Justin, Lee T Randall, Lecomte Sophie, de la Rosa Miguel A, Hildebrandt Peter, Murgida Daniel H
Abstract excerpt
The electron shuttle heme protein Cyt-c(6) from the photosynthetic cyanobacterium Nostoc sp. PCC 7119 was immobilized on nanostructured Ag electrodes coated with SAMs that mimic different possible interactions with its natural reaction partner PSI. The structure, redox potential, and electron-transfer dynamics of the SAM-Cyt-c(6) complexes were investigated by TR-SERR spectroelectrochemistry. It is shown that the...
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