Structural and Solution Speciation Studies on fac-Tricarbonylrhenium(I) Complexes of 2,2′-Bipyridine Analogues

Abstract excerpt

High Resolution Image Download MS PowerPoint Slide In this study, we report the synthesis and characterization of 12 novel rhenium(I) complexes with the general formula fac -[Re(CO) 3 (NN)X] n+ where (NN) is a 2,2′-bipyridine analogue ligand, X = Cl –, Br –, or H 2 O, and n = 0 or 1, focusing on their speciation in an aqueous solution. The prepared organorhenium complexes are stable in a wide pH range in an...

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