Allosteric regulation of epoxide opening cascades by a pair of epoxide hydrolases in monensin biosynthesis.

Abstract excerpt

Multistep catalysis of epoxide hydrolase/cyclase in the epoxide opening cascade is an intriguing issue in polyether biosynthesis. A pair of structurally homologous epoxide hydrolases was found in gene clusters of ionophore polyethers. In the epoxide opening reactions with MonBI and MonBII involve...

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