Article
X-ray structure of the metcyano form of dehaloperoxidase from Amphitrite ornata: evidence for photoreductive dissociation of the iron-cyanide bond.
Acta crystallographica. Section D, Biological crystallography - 1 Jul 2010
de Serrano V S, Davis M F, Gaff J F, Zhang Qi, Chen Z, D'Antonio E L, Bowden E F, Rose R, Franzen S
Abstract excerpt
X-ray crystal structures of the metcyano form of dehaloperoxidase-hemoglobin (DHP A) from Amphitrite ornata (DHPCN) and the C73S mutant of DHP A (C73SCN) were determined using synchrotron radiation in order to further investigate the geometry of diatomic ligands coordinated to the heme iron. The DHPCN structure was also determined using a rotating-anode source. The structures show evidence of photoreduction of...
Read the complete abstract on PubMedTopics
Share this publication in a Topic to start or enrich a Post.