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The Molecular Basis of Conjugated Polyyne Biosynthesis in Phytopathogenic Bacteria

4 Jun 2014

Abstract excerpt

Polyynes (polyacetylenes), which are produced by a variety of organisms, play important roles in ecology. Whereas alkyne biosynthesis in plants, fungi, and insects has been studied, the biogenetic origin of highly unstable bacterial polyynes has remained a riddle. Transposon mutagenesis and genome sequencing unveiled the caryoynencin (cay) biosynthesis gene cluster in the plant pathogen B. caryophylli, and...

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PMID: 24898429
DOI: 10.1002/anie.201403344

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