Article
Solid-state electron transport via cytochrome c depends on electronic coupling to electrodes and across the protein.
Proceedings of the National Academy of Sciences of the United States of America - 15 Apr 2014
Amdursky Nadav, Ferber Doron, Bortolotti Carlo Augusto, Dolgikh Dmitry A, Chertkova Rita V, Pecht Israel, Sheves Mordechai, Cahen David
Abstract excerpt
Electronic coupling to electrodes, Γ, as well as that across the examined molecules, H, is critical for solid-state electron transport (ETp) across proteins. Assessing the importance of each of these couplings helps to understand the mechanism of electron flow across molecules. We provide here experimental evidence for the importance of both couplings for solid-state ETp across the electron-mediating protein...
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