Article
Enhancement of Peroxidase Activity in Artificial Mimochrome VI Catalysts through Rational Design.
Chembiochem : a European journal of chemical biology - 4 Sept 2018
Caserta Giorgio, Chino Marco, Firpo Vincenzo, Zambrano Gerardo, Leone Linda, D'Alonzo Daniele, Nastri Flavia, Maglio Ornella, Pavone Vincenzo, Lombardi Angela
Abstract excerpt
Rational design provides an attractive strategy to tune and control the reactivity of bioinspired catalysts. Although there has been considerable progress in the design of heme oxidase mimetics with active-site environments of ever-growing complexity and catalytic efficiency, their stability during turnover is still an open challenge. Herein, we show that the simple incorporation of two 2-aminoisobutyric acids...
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