Article
Diasteltoxins A-C, Asteltoxin-Based Dimers from a Mutant of the Sponge-Associated Emericella variecolor Fungus.
Organic letters - 16 Sept 2016
Long Hailin, Cheng Zhongbin, Huang Wei, Wu Qi, Li Xiaodan, Cui Jingrong, Proksch Peter, Lin Wenhan
Abstract excerpt
Three novel asteltoxin-bearing dimers namely diasteltoxins A-C (1-3) along with asteltoxin were isolated from a mutated strain of a sponge-derived fungus Emericella variecolor XSA-07-2. Their structures were determined by extensive spectroscopic analyses including the computed electronic circular dichroism (ECD) data for the configurational assignment. The biogenetic formation of the dimers through [2 + 2]...
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