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Ru–TAP complexes and DNA: from photo-induced electron transfer to gene photo-silencing in living cells

18 Jun 2013

Abstract excerpt

In this review, examples of applications of the photo-induced electron transfer (PET) process between photo-oxidizing Ru-TAP (TAP = 1,4,5,8-tetraazaphenanthrene) complexes and DNA or oligodeoxynucleotides (ODNs) are discussed. Applications using a free Ru-TAP complex (not chemically anchored to an ODN) are first considered. In this case, the PET gives rise to the production of an irreversible adduct of the Ru...

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PMID: 23776293
DOI: 10.1098/rsta.2012.0131

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