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T-Muurolol Sesquiterpenes from the Marine <i>Streptomyces</i> sp. M491 and Revision of the Configuration of Previously Reported Amorphanes

10 Dec 2008

Abstract excerpt

Two new sesquiterpenes, 15-hydroxy-T-muurolol (3d) and 11,15-dihydroxy-T-muurolol (3e), along with the plant cadinenes T-muurolol (3f) and 3alpha-hydroxy-T-muurolol (3g), were isolated from the marine-derived Streptomyces sp. M491. Their absolute configuration was established via NMR spectroscopy and X-ray crystallography of 3-oxo-T-muurolol (3a), which was reisolated from this strain. In addition, the absolute...

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PMID: 19072130
DOI: 10.1021/np8006843

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