Article
Photogeneration and Quenching of Tryptophan Radical in Azurin.
The journal of physical chemistry. B - 23 Jul 2015
Larson Bethany C, Pomponio Jennifer R, Shafaat Hannah S, Kim Rachel H, Leigh Brian S, Tauber Michael J, Kim Judy E
Abstract excerpt
Tryptophan and tyrosine can form radical intermediates that enable long-range, multistep electron transfer (ET) reactions in proteins. This report describes the mechanisms of formation and quenching of a neutral tryptophan radical in azurin, a blue-copper protein that contains native tyrosine (Y1...
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