Article
Oxidation of methane by a biological dicopper centre.
Nature - 6 May 2010
Balasubramanian Ramakrishnan, Smith Stephen M, Rawat Swati, Yatsunyk Liliya A, Stemmler Timothy L, Rosenzweig Amy C
Abstract excerpt
Vast world reserves of methane gas are underutilized as a feedstock for the production of liquid fuels and chemicals owing to the lack of economical and sustainable strategies for the selective oxidation of methane to methanol. Current processes to activate the strong C-H bond (104 kcal mol(-1)) in methane require high temperatures, are costly and inefficient, and produce waste. In nature, methanotrophic bacteria...
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