Article
A rhodium complex-linked β-barrel protein as a hybrid biocatalyst for phenylacetylene polymerization.
Chemical communications (Cambridge, England) - 9 Oct 2012
Onoda Akira, Fukumoto Kazuki, Arlt Marcus, Bocola Marco, Schwaneberg Ulrich, Hayashi Takashi
Abstract excerpt
Our group recently prepared a hybrid catalyst containing a rhodium complex, Rh(Cp)(cod), with a maleimide moiety at the peripheral position of the Cp ligand. This compound was then inserted into a β-barrel protein scaffold of a mutant of aponitrobindin (Q96C) via a covalent linkage. The hybrid pr...
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