Article
Formation of interacting spins on flavosemiquinone and tyrosine radical in photoreaction of a blue light sensor BLUF protein TePixD.
Biochemistry - 25 Nov 2008
Nagai Hiroko, Fukushima Yoshimasa, Okajima Koji, Ikeuchi Masahiko, Mino Hiroyuki
Abstract excerpt
Light-induced radicals were detected by electron paramagnetic resonance (EPR) and pulsed electron-nuclear double resonance (ENDOR) in the BLUF-domain protein TePixD of the thermophilic cyanobacterium Thermosynechococcus elongatus BP-1. The illumination of TePixD at 5-200 K derived an EPR signal with a separation of 85 G between the main peaks around g = 2, showing a typical Pake's pattern of magnetic...
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