Article
Primary charge separation within the structurally symmetric tetrameric Chl2APAPBChl2B chlorophyll exciplex in photosystem I.
Journal of photochemistry and photobiology. B, Biology - 1 Apr 2021
Cherepanov Dmitry A, Shelaev Ivan V, Gostev Fedor E, Petrova Anastasia, Aybush Arseniy V, Nadtochenko Victor A, Xu Wu, Golbeck John H, Semenov Alexey Yu
Abstract excerpt
In Photosystem I (PS I), the role of the accessory chlorophyll (Chl) molecules, Chl2A and Chl2B (also termed A-1A and A-1B), which are directly adjacent to the special pair P700 and fork into the A- and B-branches of electron carriers, is incompletely understood. In this work, the Chl2A and Chl2B transient absorption ΔA0(λ) at a time delay of 100 fs was identified by ultrafast pump-probe spectroscopy in three...
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