Article
Primary charge separation within P870* in wild type and heterodimer mutants in femtosecond time domain.
Biochimica et biophysica acta - 1 Aug 2012
Khatypov R A, Khmelnitskiy A Yu, Khristin A M, Fufina T Yu, Vasilieva L G, Shuvalov V A
Abstract excerpt
Primary charge separation dynamics in the reaction center (RC) of purple bacterium Rhodobacter sphaeroides and its P870 heterodimer mutants have been studied using femtosecond time-resolved spectroscopy with 20 and 40fs excitation at 870nm at 293K. Absorbance increase in the 1060-1130nm region that is presumably attributed to P(A)(δ+) cation radical molecule as a part of mixed state with a charge transfer...
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