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Formicins, N -Acetylcysteamine-Bearing Indenone Thioesters from a Wood Ant-Associated Bacterium

6 Jul 2020

Abstract excerpt

Formicins A–C ( 1 – 3 ) were discovered from Streptomyces sp. associated with wood ants. The structures of 1 and 2 were elucidated as indenone thioesters bearing N -acetylcysteamine based on spectroscopic analysis. The configurations of 1 – 3 were determined by the analysis of ROESY correlations, the phenylglycine methyl ester method, and chemical derivatization from 3 to 2 . Formicin A inhibited the growth of...

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PMID: 32628492
DOI: 10.1021/acs.orglett.0c01584

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