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Article

Going beyond Structure: Nickel-Substituted Rubredoxin as a Mechanistic Model for the [NiFe] Hydrogenases.

Journal of the American Chemical Society - 15 Aug 2018

Slater Jeffrey W, Marguet Sean C, Monaco Haleigh A, Shafaat Hannah S

Abstract excerpt

Well-defined molecular systems for catalytic hydrogen production that are robust, easily generated, and active under mild aqueous conditions remain underdeveloped. Nickel-substituted rubredoxin (NiRd) is one such system, featuring a tetrathiolate coordination environment around the nickel center that is identical to the native [NiFe] hydrogenases and demonstrating hydrogenase-like proton reduction activity....

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PMID: 30016865
DOI: 10.1021/jacs.8b05194

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