Article
Non-covalent interactions in blue copper protein probed by Met16 mutation and electronic and resonance Raman spectroscopy of Achromobacter cycloclastes pseudoazurin.
Journal of inorganic biochemistry - 1 Mar 2010
Fitzpatrick Marzena B, Obara Yuji, Fujita Koyu, Brown Doreen E, Dooley David M, Kohzuma Takamitsu, Czernuszewicz Roman S
Abstract excerpt
We have used low-temperature (77K) resonance Raman (RR) spectroscopy as a probe of the electronic and molecular structure to investigate weak pi-pi interactions between the metal ion-coordinated His imidazoles and aromatic side chains in the second coordination sphere of blue copper proteins. For...
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