Article
Emergent decarboxylase activity and attenuation of α/β-hydrolase activity during the evolution of methylketone biosynthesis in tomato.
The Plant cell - 1 Apr 2012
Auldridge Michele E, Guo Yongxia, Austin Michael B, Ramsey Justin, Fridman Eyal, Pichersky Eran, Noel Joseph P
Abstract excerpt
Specialized methylketone-containing metabolites accumulate in certain plants, in particular wild tomatoes in which they serve as toxic compounds against chewing insects. In Solanum habrochaites f. glabratum, methylketone biosynthesis occurs in the plastids of glandular trichomes and begins with intermediates of de novo fatty acid synthesis. These fatty-acyl intermediates are converted via sequential reactions...
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